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Anna university 3rd semester mech mechanical engineering notes, question bank, question papers, 2&16 marks, lab manuals. The arrow of time in thermodynamics from the macroscopic and microscopic cases both follow the perceived arrow of time, which means that disorder must always increase somewhere in the universe when considering the system itself, entropy could decrease but at the expense of increasing elsewhere. Thermodynamics is a branch of physics that studies the effects of changes in temperature, pressure, and volume on physical systems at the macroscopic scale by analyzing the collective motion of their particles using statistics.